This paper focuses on a biofuel-based Multi-Energy System generating electricity, heat and hydrogen. The proposed system, that is conceived as refit option for an existing anaerobic digester plant in which the biomass is converted to biogas, consists of: i) a fuel processing unit, ii) a power production unit based on the SOFC (Solid Oxide Fuel Cell) technology, iii) a hydrogen separation, compression and storage unit. The aim of this study is to define the operating conditions that allow optimizing the plant performances by applying the exergy analysis that is an appropriate technique to assess and rank the irreversibility sources in energy processes. Thus, the exergy analysis has been performed for both the overall plant and main plant components and the main contributors to the overall losses have been evaluated. Moreover, the first principle efficiency and the second principle efficiency have been estimated. Results have highlighted that the fuel processor (the Auto-Thermal Reforming reactor) is the main contributor to the global exergy destruction (9.74% of the input biogas exergy). In terms of overall system performance the plant has an exergetic efficiency of 53.1% (it is equal to 37.7% for the H2 production).
